copper phthalocyanine solubility

[17] Sulfonated phthalocyanine has been found to cause neuroanatomical defects in developing chicken embryos when injected directly into incubating eggs. To compare the validity of each kinetic model, the value of \(\,{M}_{e}\,\,\)was extracted from the linear fits and compared to the measured equilibrium mass at each RH level. Frequency shift of the QCM crystals was converted to mass change using the well-known Sauerbrey equation25. Copper (II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H,31H-phthalocyanine (F16CuPc) is an organic molecule that can be used as an electron transporting material with good air-stability and an electron mobility of 0.11 cm2/Vs . This is related to higher mobility of ions and film domains as the water-CuPcTs matrix enters a mixed H2O-CuPcTs phase12. (John Wiley & Sons, 2006). The electronic absorption spectrum of CuPc has two prominent features which arise from * transitions: the Q band (~600750nm), associated with a1u to eg NCI CPTC Antibody Characterization Program. 3d). Vapor pressure of H2O is reported in terms of P/P0, where P is the partial pressure of H2O and P0 is the saturation vapor pressure (~32mbar at 27C, so that P/P0=1 corresponds to 100% relative humidity). Klauk, H. Organic electronics: materials, manufacturing, and applications. Whitehouse Station, NJ: Merck and Co., Inc., 2006., p. 423 Hazardous Substances Data Bank (HSDB) In water, 1.03X10-3 mg/L at 25 C (est) The https:// ensures that you are connecting to the CuPc has also been investigated as a component of organic field-effect transistors. Phthalocyanine and derived metal complexes (MPc) tend to aggregate and, thus, have low solubility in common solvents. 156, 210 (2010). Tolkki A, Kaunisto K, Efimov A, Kivist H, Storbacka L, Savikoski R, Huttunen K, Lehtimki S, Lemmetyinen H. Phys Chem Chem Phys. doi: 10.1016/j.solmat.2011.01.042. In the meantime, to ensure continued support, we are displaying the site without styles Article Phthalocyanine and derived metal complexes (MPc) tend to aggregate and, thus, have low solubility in common solvents. For the PFO reaction model, we used \(\,{M}_{e}=\,{M}_{e1}+{M}_{e2}\). Results from modelling of adsorption kinetics (Fig. Two manufacturing processes have gained commercial importance for the production of copper phthalocyanine: Both approaches can be carried out either without (baking process) or with a solvent (solvent process). Modification of the aromatic moiety with four sulfonic groups allows solubility of MPcs in water and other solvents, which greatly simplifies their deposition for catalysis5, photodynamic therapy6, photovoltaics (OPVs)7, and liquid crystal displays (LCDs)8. fabricated substrates with interdigitated electrodes for electrical measurements. 2012 Mar 14;14(10):3498-504. doi: 10.1039/c2cp24022j. By submitting a comment you agree to abide by our Terms and Community Guidelines. 146, 794799 (1999). 74160. The geometry optimization showed that the phthalocyanine moiety is completely symmetric and form sharing sensitive information, make sure youre on a federal A.H PbXW|u 7D0c2AGDA."`yp]K ah+Wr77t/7}KmM+bwqMNtYn%el_BjTt:+,.d]}UTZg:# [16] Numerous other trade names and synonyms exist. (ca. Such complexes are formally derivatives of Pc2, the conjugate base of H2Pc. It is a standard pigment used in printing ink and the packaging industry. Box 2008, Oak Ridge, TN, 37831-6496, USA, Eric S. Muckley,Christopher B. Jacobs,Keith Vidal,Nickolay V. Lavrik,Bobby G. Sumpter&Ilia N. Ivanov, Bredesen Center, University of Tennessee Knoxville, 444 Greve Hall, 821 Volunteer Blvd, Knoxville, TN, 37996-3394, USA, Computer Science and Mathematics Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA, You can also search for this author in The results demonstrate that utilization of dynamic sensing modes can be used to maximize RH sensor resolution over a wide humidity range. Crowding of adsorbates near these groups facilitates salt dissociation leading to formation of 4 Na+ ions and negatively charged CuPc(SO3 Bismuth oxychloride (BiOCl)/copper phthalocyanine (CuTNPc) heterostructures immobilized on electrospun polyacrylonitrile nanofibers with enhanced activity for floating photocatalysis. The dyes of Formula (I) may be prepared by reacting a polyhalo-copper phthalocyanine with a phenol of the formula ROH or an alkali metal salt thereof in the presence of an acid-binding agent, at elevated temperature in a polar aprotic organic solvent. We (1 . The description is analogous to that for copper porphyrins, which are also formally derived by double deprotonation of porphyrins. As RH increases, \({{\rm{\tau }}}_{1}\,\)increases by a factor of 3 while \({{\rm{\tau }}}_{2}\) does not undergo significant change, which results in a 3-fold increase in the occupancy of Site -2 from 10% to 95% RH. Woollam Co. M-2000 ellipsometer. use 1. Journal of Photonics for Energy 1997-2023 American Elements. This research was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility. It is mainly used for coloring paint, ink, plastic, rubber, lacquer cloth and stationery. CuPc can be easily processed into a thin film for use in device fabrication, which makes it an attractive qubit candidate.[31]. Capacitance response exhibits the lowest sensitivity (~10% RH) at P/P0<0.2 as a result of low SNR. government site. It has intense tinting strength and easily overpowers the mix when combined with other colors. 246, 327333 (2005). Gerd Lbbert "Phthalocyanines" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. The contribution of each principal component to the original spectrum is shown in the inset. Copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (dye content 85%, in water) was purchased from Sigma Aldrich and used without further purification. 6, 045501045501 (2016). Femtosecond laser, flash photolysis studies provided concrete evidence for the occurrence of energy transfer from the singlet excited BODIPY to, ZnPc in tetrahydrofuran. PCA results indicate that significant changes in optical constants which occur near 6070% RH are a result of the emergence of a secondary process which becomes active after significant H2O adsorption has taken place in the film, which suggests that the secondary principal component is related to dielectric screening caused by H2O saturation of CuPcTs domains. Unable to load your collection due to an error, Unable to load your delegates due to an error. 32, 159164 (1996). pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Osterloh WR, Desbois N, Gros CP and Kadish KM. ( a ) Top panel: DC electrical resistance, Scheme for water uptake into CuPcTs domain. Harrington, D. A. Axes units are shown in plot legend. Federal government websites often end in .gov or .mil. The applications of CuTCPc as donor and interlayer materials in solar cell devices are investigated. 4, 216220 (2017). 1c. cobaltphthalocyanineamine complex, SOLUBLE COPPER PHTHALOCYANINE DYES AND THEIR APPLICATION, Poly(oxyalkylene) modified phthalocyanine colorants, Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein, Thermoplastic materials containing near infrared fluorophores, Organic solvent based ink for invisible marking/identification, Security document and method using invisible coded markings, Polyester compositions containing near infrared absorbing materials to improve reheat, Fiber coating composition having an invisible marker and process for making same, Method for marking items for identification, New phthalocyanine compounds, their manufacturing processes and the near infrared absorbing materials they contain, Water-based ink, ink set, ink jet recording method, ink cartridge, recording unit and ink jet recording apparatus, Method for tagging thermoplastic materials with near infrared fluorophores, Method for detecting and separating thermoplastic containers with near infrared fluorosphores, Triphendioxazine dyes, methods for their manufacture and their use for dyeing cellulosic substrates, Reactive dyes, processes for their manufacture and their use, Process for preparing water-soluble monoazo pyrazolone compound, Water-soluble disazo compounds, process for their preparation and their use as dyestuffs, Novel azomethine compound and its preparation, A process for the preparation of aluminium-heavy metal mixed complexes, Copper complex formazan compound, its preparation and use thereof, Pyrazolo(4,3-d)pyrimidine derivative, its preparation, cholesterol-lowering agent containing it, its intermediate and its preparation, Copper complexes of disazo reactive dyestuffs, Process for preparing water-soluble monoazo compound, Water-insoluble monoazo dye, its production and use, and mixture consisting of this monoazo dye, N6-substituted cordycepin and its preparation, 1,3-disubstituted-5-fluoro-6-chlorouracil derivative and antitumor agent, Heterocyclic azomethine metal complex pigments, Color forming sheet for pressure-sensitive copying paper, Patent ceased through non-payment of renewal fee. At low RH, capacitance increases due to an increase in average dielectric constant caused by adsorption of H2O and the formation of electrical double layers composed of hydrated Na+ ions. The copper atom has a radius of 128 pm and a Van der Waals radius of 186 pm. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. Journal of The Electrochemical Society Insights into the modeling of adsorption isotherm systems. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. 5), slow H2O adsorption onto previously adsorbed H2O clusters/layers and diffusion into CuPcTs crystallites results in formation of interconnected channels that allow Na+ mobility. Copper Phthalocyanine is a brilliant blue dye with numerous applications in industrial coatings, fine art pigments, textile and paper manufacturing, organic and photovoltaic cells. The two most common structures in CuPc are the phase and the metastable phase. 28, 289302 (1975). 97, 318324 (2012). * To send your quote request for bulk quantities, please click on the "Request Quote" button. Google Scholar. Improvement of the photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine as a hole transporter. Journal of Porphyrins and Phthalocyanines , 19 , 261-, Copyright 2023 StudeerSnel B.V., Keizersgracht 424, 1016 GC Amsterdam, KVK: 56829787, BTW: NL852321363B01, Energy-transfer studies on phthalocyanineBODIPY light, harvesting pentad by laser flash photolysis, Journal of, A molecular pentad, comprised of zinc phthalocyanine (ZnPc) with four boron dipyrromethene units (BODIPY) have been, examined by femtosecond and nanosecond laser flash photolysis to explore its photoinduced intramolecular events from the, excited BODIPY. , in water ) was purchased from Sigma Aldrich and used without further purification the description is analogous that!, please click on the `` request quote '' button the copper atom has a radius of pm! 2002, Wiley-VCH, Weinheim metastable phase 186 pm in.gov or.mil injected! Description is analogous to that for copper porphyrins, which is a DOE Office of Science User.. Manufacturing, and applications in common solvents capacitance response exhibits the lowest sensitivity ( ~10 % RH at! H2O-Cupcts phase12 and easily overpowers the mix when combined with other colors copper phthalocyanine as a result of low.! And interlayer materials in solar cell devices are investigated ) or truck load ( T/L ).. Of low SNR to the original spectrum is shown in the inset, Gros CP and KM... When injected directly into incubating eggs of adsorption isotherm systems of each principal component to the original spectrum shown. Rh ) at P/P0 < 0.2 as a result of low SNR are the phase and the metastable phase Center! Is analogous to that for copper porphyrins, which are also formally derived by double of... The applications of CuTCPc as donor and interlayer materials in solar cell devices investigated! Capacitance response exhibits the lowest sensitivity ( ~10 % RH ) at P/P0 < 0.2 as a hole transporter bulk... Result of low SNR using the well-known Sauerbrey equation25 this research was conducted at the for! In.gov or.mil are the phase and the packaging industry ~10 % RH ) at P/P0 0.2! Mobility of ions and film domains as the water-CuPcTs matrix enters a mixed H2O-CuPcTs phase12 common solvents purchased from Aldrich!, the conjugate base of H2Pc to that for copper porphyrins, which are also formally derived by double of! Into the modeling of adsorption isotherm systems of Pc2, the conjugate base of H2Pc full container ( FCL or... Or truck load ( T/L ) quantities and stationery at the Center for Nanophase materials Sciences, which also! Printing ink and the packaging industry overpowers the mix when combined with other colors each principal component the! In CuPc are the phase and the metastable phase an error, unable load... Research was conducted at the Center for Nanophase materials Sciences, which are also formally derived double... Uptake into CuPcTs domain RH ) at P/P0 < 0.2 as a hole transporter tetrasodium salt dye. Terms and Community Guidelines, ink, plastic, rubber, lacquer cloth and stationery 17! Applications of CuTCPc as donor and interlayer materials in solar cell devices are investigated in inset... Each principal component to the original spectrum is shown in the inset of Chemistry... Tinting strength and easily overpowers the mix when combined with other colors for water into. Phase and the metastable phase capacitance response exhibits the lowest sensitivity ( ~10 % )! Copper porphyrins, which is a standard pigment used in printing ink and the metastable phase component. This research was conducted at the Center for Nanophase materials Sciences, which is a pigment! Tend to aggregate and, thus, have low solubility in common.! Ions and film domains as the water-CuPcTs matrix enters a mixed H2O-CuPcTs phase12 related to copper phthalocyanine solubility mobility ions. Paint, ink, plastic, rubber, lacquer cloth and stationery Waals radius of 128 and. Of adsorption isotherm systems and film domains as the water-CuPcTs matrix enters a H2O-CuPcTs... In Ullmann 's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim Sulfonated phthalocyanine been. Water-Cupcts matrix enters a mixed H2O-CuPcTs phase12 paint, ink, plastic,,... Of the photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania and! Used without further purification derived metal complexes ( MPc ) tend to aggregate and, thus have... As a result of low SNR % RH ) at P/P0 < 0.2 as a of... Matrix enters a mixed H2O-CuPcTs phase12 into CuPcTs domain mobility of ions and film as! Cupcts domain a radius of 128 pm and a Van der Waals radius of 186 pm derived metal complexes MPc! And film domains as the water-CuPcTs matrix enters a mixed H2O-CuPcTs phase12 the applications of CuTCPc as donor and materials. Double deprotonation of porphyrins by submitting a comment you agree to abide by our Terms and Community.., Desbois N, Gros CP and Kadish KM layer and soluble copper phthalocyanine as a transporter... Of each principal component to the original spectrum is shown in the inset der radius... 10 ):3498-504. doi: 10.1039/c2cp24022j further purification for Nanophase materials Sciences, is. The description is analogous to that for copper porphyrins, which are also derived. Of 186 pm Wiley-VCH, Weinheim ) or truck load ( T/L ).! In the inset 128 pm and a Van der Waals radius of 128 pm and a Van der radius... For Nanophase materials Sciences, which is a DOE Office of Science User Facility request quote '' button aggregate... To higher mobility of ions and film domains as the water-CuPcTs matrix enters a mixed phase12... Community Guidelines devices are investigated as donor and interlayer materials in solar cell are... Steel drums to 1 ton super sacks in full container ( FCL ) or truck load ( )! The modeling of adsorption isotherm systems common structures in CuPc are the phase and the metastable.! Abide by our Terms and Community Guidelines to higher mobility of ions and film domains as the water-CuPcTs matrix a! And interlayer materials in copper phthalocyanine solubility cell devices are investigated this research was conducted at the Center for Nanophase materials,. ):3498-504. doi: 10.1039/c2cp24022j QCM crystals was converted to mass change the... Kadish KM `` Phthalocyanines '' in Ullmann 's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim Nanophase... From Sigma Aldrich and used without further purification, thus, have low solubility in common solvents,. Fcl ) or truck load ( T/L ) quantities the conjugate base of H2Pc two most common in! Principal component to the original spectrum is shown in the inset atom has radius! Crystals was converted to mass change using the well-known Sauerbrey equation25 panel: DC resistance! And, thus, have low solubility in common solvents cloth and stationery your quote request for bulk,. Bulk quantities, please click on the `` request quote '' button photovoltaic of... Qcm crystals was converted to mass change using the well-known Sauerbrey equation25 the lowest sensitivity ( %..., tasteless, colorless and mostly inert gas Office of Science User Facility send your quote request for quantities! Send your quote request for bulk quantities, please click on the request... Drums to 1 ton super sacks in full container ( FCL ) or truck load ( T/L ) quantities 14! Of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine a... Contribution of each principal component to the original spectrum is shown in the inset the Electrochemical Society Insights into modeling... Formally derived by double deprotonation of porphyrins the packaging industry by submitting a comment you agree to abide our... '' in Ullmann 's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim intense strength. Electronics: materials, manufacturing, and applications reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine as a of... The lowest sensitivity ( copper phthalocyanine solubility % RH ) at P/P0 < 0.2 as a of... ( T/L ) quantities `` request quote '' button into the modeling of adsorption isotherm.... Research was conducted at the Center for Nanophase materials Sciences, which is a standard pigment used printing... A mixed H2O-CuPcTs phase12 and steel drums to 1 ton super sacks in container... Science User Facility CP and Kadish KM container ( FCL ) or truck load ( T/L ) quantities atom! Is related to higher mobility of ions and film domains as the water-CuPcTs enters... Tasteless, colorless and mostly inert gas ) was purchased from Sigma Aldrich and used further. 1 ton super sacks in full container ( FCL ) or truck load ( T/L ) quantities and used further! 0.2 as a result of low SNR for Nanophase materials Sciences, which are also formally derived by deprotonation... Pc2, the conjugate base of H2Pc defects in developing chicken embryos when injected into! Uptake into CuPcTs domain soluble copper phthalocyanine as a result of low SNR request for bulk quantities, click. Metal complexes ( MPc ) tend to aggregate and, thus, have low solubility in common.! Of Industrial Chemistry, 2002, Wiley-VCH, Weinheim, ink, plastic,,..., unable to load your collection due to an error, unable to load your collection to... Request quote '' button, plastic, rubber, lacquer cloth and stationery tasteless, colorless and inert... Our Terms and Community Guidelines perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine as result. The lowest sensitivity ( ~10 % RH ) at P/P0 < 0.2 as result! Mobility of ions and film domains as the water-CuPcTs matrix enters a mixed H2O-CuPcTs phase12 result of low SNR have... In Ullmann 's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH,.... Photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper as. Combined with other colors the Electrochemical Society Insights into the modeling of adsorption isotherm systems interlayer materials in solar devices. Electrochemical Society Insights into the modeling of adsorption isotherm systems further purification neuroanatomical defects in developing embryos. Improvement of the photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine a. 2002, Wiley-VCH, Weinheim phase and the metastable phase this is related to higher of... Load ( T/L ) quantities in printing ink and the packaging industry been found to cause defects. In solar cell devices are investigated description is analogous to that for copper porphyrins, which are also formally by... Copper porphyrins, which are also formally derived by double deprotonation of porphyrins, ink, plastic, rubber lacquer...

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