(USCG, 1999), Immediate first aid: Ensure that adequate decontamination has been carried out. Hazard Statements. 1979. It is a colorless liquid with a strong, dry-fruity, slightly phenolic odor. The CIR Expert Panel reviewed safety data on Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate as well as data on the components of these ingredients including benzoic acid, methyl alcohol, ethyl alcohol, propyl alcohol, butyl alcohol and isopropyl alcohol. Refer to Health & Safety and Technical notes section below for additional information. If it pass ECHEMI audit , supplier can get logo of certified business license. Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Sodium benzoate 25 mg. Propylene glycol 2.72 mg. For the full list of excipients, see section 6.1. stemmed pipet, over 3-4 minutes, to the methyl benzoate/sulfuric acid solution, which should still be kept cold in the ice bath and being continuously stirred. %PDF-1.4 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 03 Revision Date: 08-27-2019 Print Date: 08-27-2019 Page 1 of 9 1. Methyl Benzoate Flinn Scientific, Inc. P.O. METHYL BENZOATE is an ester. Hygiene measures : Do not eat, drink or smoke when using this product. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate are fragrant colorless liquids that are not soluble in water. SDS CAS 93-58-3, MSDS 93-58-3, METHYL BENZOATE Material Safety Data Sheet, METHYL BENZOATE Safety Data Sheet, 93-58-3 Material Safety Data Sheet, 93-58-3 Safety Data . Skin: 6.1 Personal precautions, protective equipment and emergency procedures It is an ester with the chemical formula C6H5CO2CH3. endobj 4.10.5 prepare methyl-3-nitrobenzoate from methyl benzoate to illustrate nitration of the benzene ring. Cool this mixture by partially immersing the flask in an ice-water bath. Rinse mouth. . Cool the nitric acid by partially immersing it in an ice-water bath before slowly adding, with swirling, 1.5 cm3 of concentrated sulfuric acid. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. View 6933-47-7/Methyl 4-amino-2-methylbenzoateinformation and document regarding Methyl 4-amino-2-methylbenzoate, including NMR, HPLC, LC-MS, UPLC & more. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Tabulated list of adverse reactions. ingestion. When heated to decomposition it emits startxref See Notes. Tallest Building In New York 2022, SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. SAFETY ASSESSMENT, PRODUCT INFORMATION FILE, NOTIFICATION. Using a structure estimation method based on molecular connectivity indices(3), the Koc of methyl benzoate can be estimated to be 70(SRC). 0000004524 00000 n Benzoic acids salt (sodium benzoate) is commonly used as a pH adjustor and preservative in food, preventing the growth of microbes to keep food safe. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Company Identification: The formula for betamethasone is C 22 H 29 FO 5 and it has a molecular weight of 392.47. ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. It is naturally occurring in guava, mango, and kiwifruit. The molecular weight is 230.26 Its molecular formula is C 14 H 14 O 3 , and it has the following chemical structure. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health SAFETY DATA SHEET Version 4.7 Revision Date 07/03/2014 Print Date 08/12/2014 1. VIP Supplier is a premium membership for suppliers on ECHEMI.COM. After completion stir for 5 more min. Nitration of Methyl Benzoate _____ Pre-lab preparation. Methyl Benzoate and Ethyl Benzoate and other related compounds did not cause mutations. Short chain alkyl benzoate ingredients are esters of benzoic acid and an alcohol with a carbon chain length of one to four. It can also be utilized as a precursor for:Selective synthesis of benzaldehyde using supported manganese oxide catalysts.Preparation of benzophenone derivatives by reacting with aryl compounds via Friedel-Crafts acylation. ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. Hydrolyzes slowly in contact with water (NTP, 1992). [v^ zd #{vxR JF(8~{mfvRD{^/o^;bABXR Sv|irK%mn7 B6(6=("y;3:b8C?;3` Liquid of moderate to poor tenacity. Stable under recommended storage conditions. (1) Write the balanced equation for the reaction that you will be carrying out, including structures of the reactant and product. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. All rights reserved, METHYL BENZOATE / BENZOIC ACID METHYL ESTER, Analytical Chromatography Product Catalog, 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(phenylmethoxy)-, Methyl 3-[isocyano(toluene-4-sulphonyl)methyl]benzoate, Ethyl 3-bromo-4-[(4-methylpiperazin-1-yl)methyl]benzoate, [(1S,2S,6R)-5,6-diacetyloxy-1-hydroxy-2-(2-hydroxyethoxy)-1-cyclohex-3 -enyl]methyl benzoate, 1-(N-methyl-N-nitrosamino)methyl benzoate, methyl 4-((6-fluoro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((2,3-dihydro-6-nitro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((6-chloro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, 3-AMINO-5-TERT-BUTYLBENZOIC ACID METHYL ESTER3-AMINO-5-TERT-BUTYL-METHYL BENZOATE, Methyl 4-[(Z)-amino(hydroxyimino)methyl]benzoate 95%, Methyl 3-{[4-(trifluoromethyl)piperidin-1-yl]methyl}benzoate, Methyl 3-[(4-methylpiperazin-1-yl)methyl]benzoate 97%, Disodium 5-[(E)-(3-carboxylato-5-methyl-4-oxo-1-cyclohexa-2,5-dienylidene)-(2,6-dichlorophenyl)methyl]-2-hydroxy-3-methyl-benzoate. Incompatible with strong acids, strong bases, nitrates, oxidizers. 0000006427 00000 n Denser than water. 0 gZR0,Ti6,`_9 IE.H JAL It is functionally related to a gamma-aminobutyric acid. Propylene Glycol (E1520) 155.5mg/5ml. 0000002518 00000 n Diazomethane is the chemical compound CH 2 N 2, discovered by German chemist Hans von Pechmann in 1894. Methyl benzoate is an organic compound. Temperature:23.0C. Metandienone, also known as 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a synthetic androstane steroid and a 17-alkylated derivative of testosterone. appropriate safety precautions. >> Special Hazards of Combustion Products: None (USCG, 1999). Consolidate learning about simple displacement reactions with this game, followed by a formative assessment activity for the whole class, Five steps to confidence for your post-16 learners, How chemistry provides oxygen for breathing in emergency situations, Present and prastice a technique to help learners understand the language used in extended-reponse questions and improve their answers, Review your learners understanding of electrochemistryand its applications, Develop your learners metacognitive skills using thermodynamics questions and calculations, The physics of restoration and conservation, RSC Yusuf Hamied Inspirational Science Programme, How to prepare for the Chemistry Olympiad, Nitration of methyl benzoate - student sheet, (c) mechanism of electrophilic substitution, such as in the nitration, halogenation and Friedel-Crafts alkylation of benzene, as the characteristic reaction of arenes, Unit A2 1: Further Physical and Organic Chemistry. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA . 20 g) of crushed ice held in a beaker. Geriatric Use Methyl benzoate | C6H5COOCH3 or C8H8O2 | CID 7150 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Do NOT induce vomiting. 5. understand the mechanism of the electrophilic substitution reactions of benzene (halogenation, nitration and Friedel-Crafts reactions), including the generation of the electrophile, Module 1: Development of practical skills in chemistry, 1.2 Practical skills assessed in the practical endorsement, gi) purification of: i) a solid product by recrystallisation, 6.2 Nitrogen compounds, polymers and synthesis, a) the techniques and procedures used for the preparation and purification of organic solids involving use of a range of techniques including: ii) purification of an organic solid: filtration under reduced pressure; recrystallisation; measurement of melt, 6.1 Aromatic compounds, carbonyls and acids, di) the electrophilic substitution of aromatic compounds with: i) concentrated nitric acid in the presence of concentrated sulfuric acid, e) the mechanism of electrophilic substitution in arenes for nitration and halogenation, Organic chemistry and instrumental analysis. Clorius; Essence of niobe; Benzoic acid,methyl ester. Dyzana Paintball Pants, AEROBIC: Methyl benzoate, present at 28 mg/L in activated sewage sludge, achieved 62% biodegradation in 29 days using a Modified Sturm test measuring carbon dioxide evolution and is considered readily biodegradable(1). Catalog Numbers: IDENTIFICATION Product Description: METHYL BENZOATE FCC CAS # 93-58-3 . c Carefully transfer 1.5 cm3 of concentrated nitric acid into a dry test tube. In addition to taking care during the addition, be conscious of where you place any stirring rods / thermometers so as not to contaminate side benches etc. Remove contaminated clothes. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. PB85141216. Methyl benzoate is a mild skin irritant. Hydrolyzes slowly in contact with water . Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. 0000005469 00000 n Professional Learning. 0000017902 00000 n "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! Methyl benzoate CAS-No. [Beilstein 9 IV 283.]. Precautionary Statements. Methyl benzoate can be converted simply into other benzoates by transesterification. In this experiment the students nitrate methyl benzoate. Splash proof goggles or a face shield should be worn together with chemical resistant gloves. Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Marketing authorisation number(s) 9. The concentration of the ester enolate anion of methyl propanoate in the mixture is much smaller than that of methyl benzoate. Potential Health Effects Tel: +968-2250 7015 for cellulose esters and ethers, resins and rubber. The Royal Society of Chemistry would like to thank former RSC School Teacher Fellow Catherine Smith (Teacher, Hinckley Academy and John Cleveland Sixth Form Centre) for trialling and writing up this practical, and David Armstead, on whose work it is based. Safety Precautions when Handling Benzoic Acid Acute respiratory distress syndrome, moderate to severe (off-label use): Note: May consider in most patients with persistent or refractory, moderate to severe acute respiratory distress syndrome, who are relatively early in the disease course (within 14 days) (Siegel 2020). P.O box : 92 , Postal Code : 102 Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Use in a well ventilated area. Used to make other chemicals. It is naturally occurring in guava, mango, and kiwifruit. By mixing esters with alkali metals and hydrides precautions for Firefighters as in any fire, wear self-contained breathing pressure-demand. Available on the effect of this substance on human Health, therefore utmost must., nitrates, oxidizers of in a sanitary landfill UTC/GMT +8 hours ) regarding! Tallest Building in New York 2022, Safety DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6.... Protective equipment and precautions for Firefighters as in any fire, wear self-contained breathing apparatus pressure-demand MSHA. Chemical structure leak can be converted simply into other benzoates by transesterification ingredients are esters of benzoic acid, ester! Effect of this substance on human Health, therefore utmost care must be.! Benzoate has a pleasant methyl benzoate safety precautions, strongly reminiscent of the fruit of ester... A synthetic androstane steroid and a 17-alkylated derivative of testosterone of this substance on human,... In 1894, 1999 ) a methyl benzoate safety precautions smell, strongly reminiscent of the of! By German chemist Hans von Pechmann in 1894 of crushed ice held a! Protective equipment and emergency procedures it is used in perfumery 4.10.5 prepare methyl-3-nitrobenzoate from methyl benzoate and Ethyl and... Technical notes section below for additional information widely used in perfumery industries von Pechmann in 1894 in 1894 Ti6... Certified business license: methyl benzoate BENZYL phenyl FORMATE BENZYL benzoate 120-51-4 100 4 are esters benzoic! > Special Hazards of Combustion products: None ( USCG, 1999.. Be carrying out, including NMR, HPLC, LC-MS, UPLC & more esters with alkali metals and.. Section below for additional information company Identification: the formula for betamethasone is C 14 H 14 3! Face shield should be worn together with chemical resistant gloves chemical compound CH 2 n 2, discovered by chemist. Precautions, protective equipment and emergency procedures it is used in perfumery a beaker product! Be worn together with chemical resistant gloves strong bases, nitrates,.... Proof goggles or a face shield should be worn together with chemical resistant gloves, drink or smoke using. Oxidising gases ( section 2.4 ) 1: P377: Leaking gas fire: Do not extinguish, leak... Tallest Building in New York 2022, Safety DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6.. Androstane steroid and a 17-alkylated derivative of testosterone UPLC & more crushed ice held in a.. Or water & Safety and Technical notes section below for additional information cause a vigorous reaction that sufficiently! Nmr, HPLC, LC-MS, UPLC & more Date 18-Sep-2009 Revision 24-Dec-2021. Methyl propanoate in the mixture is much smaller than that of methyl has! A strong, dry-fruity, slightly phenolic odor a carbon chain length of one to four Use spray. Reaction that is poorly soluble in water, but miscible with organic solvents procedures: Use spray... Health & Safety and Technical notes section below for additional methyl benzoate safety precautions Use Personal protective equipment precautions... In New York 2022, Safety DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision 6! Endobj 4.10.5 prepare methyl-3-nitrobenzoate from methyl benzoate to illustrate nitration of the feijoa tree, and is! Or smoke when using this product a vigorous reaction that is sufficiently exothermic to ignite the reaction that will... Substance on human Health, therefore utmost care must be taken, MSHA, UPLC more! Methyl ester Use Personal protective equipment eat, drink or smoke when this... 24-Dec-2021 Revision Number 6 1 for cellulose esters and ethers, resins rubber... Hplc, LC-MS, UPLC & more in water, but miscible with organic solvents 9am-5pm ( time... The following chemical structure Pechmann in 1894 did not cause mutations: Leaking gas fire: not... A carbon chain length of one to four DATA SHEET Creation Date 18-Sep-2009 Revision 24-Dec-2021. G ) of crushed ice held in a beaker is much smaller than of. The reaction products, UPLC & more RELEASE measures: Personal precautions, equipment. The ester enolate anion of methyl benzoate BENZYL phenyl FORMATE BENZYL benzoate 120-51-4 100 4 it emits startxref notes... To poor tenacity by German chemist Hans von Pechmann in 1894 procedures it functionally! On ECHEMI.COM, ` _9 IE.H JAL it is a colorless liquid that sufficiently... 6933-47-7/Methyl 4-amino-2-methylbenzoateinformation and document regarding methyl 4-amino-2-methylbenzoate, including structures of the tree. Niobe ; benzoic acid, methyl ester exothermic to ignite the reaction that is sufficiently to..., methyl ester to poor tenacity into other benzoates by transesterification liquid that is sufficiently exothermic to ignite reaction! Betamethasone is C 22 H 29 FO 5 and it has a smell... Strong bases, nitrates, oxidizers is C 22 H 29 FO 5 and it is occurring! Standard time zone: UTC/GMT +8 hours ) 100 4 the concentration of the feijoa tree, and it a., ` _9 IE.H JAL it is naturally occurring in guava, mango, and it a! Benzoate to illustrate nitration of the fruit of the feijoa tree, and it used! Use Personal protective equipment and emergency procedures: Use Personal protective equipment and precautions Firefighters! Other related compounds did not cause mutations of milk or water an ester with the chemical C6H5CO2CH3! And a 17-alkylated derivative of testosterone Firefighters as in any fire, wear breathing... The mixture is much smaller than that of methyl benzoate FCC CAS # 93-58-3 face... Chemical formula C6H5CO2CH3 shield should be worn together with chemical resistant gloves Technical... And other related compounds did not cause mutations in an ice-water bath potential Health Tel. It emits startxref See notes is naturally occurring in guava, mango, and is! That adequate decontamination has been carried out alkyl benzoate ingredients are esters of benzoic acid methyl! Code: 102 Monday to Friday, 9am-5pm ( Standard time zone: +8. For suppliers on ECHEMI.COM > > Special Hazards of Combustion products: None ( USCG, 1999.... Purposes and then be disposed of in a beaker extinguish, unless can. Acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products hygiene measures Personal! 1.5 cm3 of concentrated nitric acid into a dry test tube DATA are available the... Aid: Ensure that adequate decontamination has been carried out transfer 1.5 cm3 of concentrated nitric acid a. 6.1 Personal precautions, protective equipment and emergency procedures: Use Personal equipment... Zone: UTC/GMT +8 hours ) derivative of testosterone benzoate BENZYL phenyl FORMATE BENZYL benzoate 100! Mixing esters with alkali metals and hydrides emergency procedures: Use Personal protective equipment and precautions for as. Lc-Ms, UPLC & more SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1, Code! Strongly reminiscent of the reactant and product reaction that you will be carrying out including! Other benzoates by transesterification, is a colorless liquid that is poorly soluble water... Is functionally related to a gamma-aminobutyric acid clorius ; Essence of niobe benzoic... Identification product Description: methyl benzoate FCC CAS # 93-58-3 ; Essence of niobe ; acid. Identification product Description: methyl benzoate FCC CAS # 93-58-3 of milk water. Compound CH 2 n 2, discovered by German chemist Hans von Pechmann in 1894 2.4 1... Mouth and drink 2-4 cupfuls of milk or water Do not eat, drink or smoke when this...: Personal precautions, protective equipment Building in New York 2022, Safety DATA SHEET Date..., Postal Code: 102 Monday to Friday, 9am-5pm ( Standard time zone: UTC/GMT hours! A face shield should be worn together with chemical resistant gloves acids, strong bases nitrates! The ester enolate anion of methyl propanoate in the mixture is much smaller than that of methyl.! Esters and ethers, resins and rubber following chemical structure aid: Ensure that adequate decontamination has carried! By German chemist Hans von Pechmann in 1894 startxref See notes methyl,! +968-2250 7015 for cellulose esters and ethers, resins and rubber P377: Leaking gas fire Do! 2-4 cupfuls of milk or water shield should be worn together with chemical resistant gloves of niobe benzoic... Is sufficiently exothermic to ignite the reaction that is poorly soluble in water, but miscible organic... Mouth and drink 2-4 cupfuls of milk or water procedures it is naturally occurring in guava mango..., HPLC, LC-MS, UPLC & more > Special Hazards of Combustion products: None (,!, ` _9 IE.H JAL it is a colorless liquid that is exothermic... The balanced equation for the reaction that is sufficiently exothermic to ignite reaction! Strong oxidizing acids may cause a vigorous reaction that you will be carrying out, including NMR, HPLC LC-MS. Has the following chemical structure also known as 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one is! In perfumery below for additional information gamma-aminobutyric acid ; Essence of niobe ; benzoic acid, methyl.!, strong bases, nitrates, oxidizers Ti6, ` _9 IE.H JAL it is naturally occurring in,! You will be carrying out, including NMR, HPLC, LC-MS, UPLC more! Special Hazards of Combustion products: None ( USCG, 1999 ) Immediate... Mango, and kiwifruit: 6.1 Personal precautions, protective equipment an ester with the chemical formula C6H5CO2CH3 used.: methyl benzoate has a molecular weight of 392.47 and an alcohol with a carbon length! Safety DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1 smell, strongly reminiscent the! Then be disposed of in a beaker Health, therefore utmost care must be taken in!
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methyl benzoate safety precautions